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Direct evidence for an iron(IV)-oxo porphyrin π-cation radical as an active oxidant in catalytic oxygenation reactions

Title
Direct evidence for an iron(IV)-oxo porphyrin π-cation radical as an active oxidant in catalytic oxygenation reactions
Authors
Han A.-R.Jin Jeong Y.Kang Y.Yoon Lee J.Sook Seo M.Nam W.
Ewha Authors
남원우서미숙
SCOPUS Author ID
남원우scopus
Issue Date
2008
Journal Title
Chemical Communications
ISSN
1359-7345JCR Link
Citation
no. 9, pp. 1076 - 1078
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
A high-valent iron(iv)-oxo porphyrin π-cation radical is an active oxidant in the catalytic oxygenation of organic substrates by an iron(iii) porphyrin complex and peracids, whereas an iron(iii)-oxidant porphyrin adduct is a sluggish oxidant in iron porphyrin model reactions. © The Royal Society of Chemistry.
DOI
10.1039/b716558g
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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