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Surface-modified imogolite by 3-APS-OsO4 complex: Synthesis, characterization and its application in the dihydroxylation of olefins

Title
Surface-modified imogolite by 3-APS-OsO4 complex: Synthesis, characterization and its application in the dihydroxylation of olefins
Authors
Qi X.Yoon H.Lee S.-H.Yoon J.Kim S.-J.
Ewha Authors
김성진윤주영
SCOPUS Author ID
김성진scopus; 윤주영scopus
Issue Date
2008
Journal Title
Journal of Industrial and Engineering Chemistry
ISSN
1226-086XJCR Link
Citation
vol. 14, no. 1, pp. 136 - 141
Indexed
SCIE; SCOPUS; KCI WOS scopus
Abstract
We modified the surface of imogolite nanorods by silylation using 3-aminopropyltriethoxysilane (3-APS) and subsequent attachment of osmium tetroxide (OsO4) onto the amine groups of the silylated imogolite surface. In order to characterize surface-modified imogolite by 3-APS-OsO4 complex, powder X-ray diffraction (powder XRD), Fourier transform infrared (FT-IR) spectroscopy, ultraviolet/visible (UV-vis) spectroscopy and X-ray photoelectron spectroscopy (XPS) experiments were carried out, and we verified the formation of the osmium tetroxide complex on the surface-modified imogolite by 3-APS. As a heterogeneous catalyst, this osmium-bound imogolite (I-APS-OsO4) was applied in the achiral dihydroxylation of olefins, and revealed excellent catalytic activity while leaching of osmium was observed. Introduction of chelating ligands instead of the primary amine group to improve the reusability of the catalyst is currently in progress. © 2007 The Korean Society of Industrial and Engineering Chemistry.
DOI
10.1016/j.jiec.2007.08.010
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자연과학대학 > 화학·나노과학전공 > Journal papers
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