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Intermetal oxygen atom transfer from an (FeO)-O-V complex to a Mn-III complex: an experimental and theoretical approach

Title
Intermetal oxygen atom transfer from an (FeO)-O-V complex to a Mn-III complex: an experimental and theoretical approach
Authors
Hong, SeungwooJang, Soo JeongCho, Kyung-BinNam, Wonwoo
Ewha Authors
남원우
SCOPUS Author ID
남원우scopus
Issue Date
2016
Journal Title
CHEMICAL COMMUNICATIONS
ISSN
1359-7345JCR Link1364-548XJCR Link
Citation
vol. 52, no. 88, pp. 12968 - 12971
Publisher
ROYAL SOC CHEMISTRY
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Oxygen atom transfer (OAT) reaction between an (FeO)-O-V complex and a Mn-III complex resulted in the eventual formation of their corresponding Fe-III and (MnO)-O-V complexes. The reaction proceeded via an initial fast OAT reaction between the (FeO)-O-V and Mn-III complexes, yielding a half equivalent of a (MnO)-O-V complex and a mu-oxo bridged Fe-IV dimer. The dimer regenerated the (FeO)-O-V species via equilibrium, which then reacted with the remaining Mn-III complex to produce another half equivalent of the (MnO)-O-V complex.
DOI
10.1039/c6cc07152j
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자연과학대학 > 화학·나노과학전공 > Journal papers
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