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Tetra-μ-benzoato-bis-[(3-methyl-quinoline)copper(II)](Cu - Cu)

Title
Tetra-μ-benzoato-bis-[(3-methyl-quinoline)copper(II)](Cu - Cu)
Authors
Park B.K.Jang K.-H.Kim P.-G.Kim C.Kim Y.
Ewha Authors
김영미
SCOPUS Author ID
김영미scopus
Issue Date
2008
Journal Title
Acta Crystallographica Section E: Structure Reports Online
ISSN
1600-5368JCR Link
Citation
vol. 64, no. 9
Indexed
SCOPUS WOS scopus
Abstract
In the title compound, [Cu2(C7H5O2)4(C10H9N)2], the paddle-wheel-type dinuclear complex mol-ecule contains four bridging benzoate groups and two terminal 3-methyl-quinoline ligands. The asymmetric unit contains one and a half mol-ecules with a total of three independent Cu atoms; there is an inversion center at the mid-point of the Cu⋯Cu bond in one molecule. The octa-hedral coordination of each Cu atom, with four O atoms in the equatorial plane, is completed by an N atom of a 3-methyl-quinoline ligand [Cu - N = 2.190 (4)-2.203 (3) Å] and by another Cu atom [Cu⋯Cu = 2.667 (1) and 2.6703 (7) Å]. The Cu atoms are all ca 0.22 Å out of the plane of the four bonded O atoms.
DOI
10.1107/S1600536808024859
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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