Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김성진 | * |
dc.contributor.author | 김영미 | * |
dc.date.accessioned | 2016-12-06T02:12:24Z | - |
dc.date.available | 2016-12-06T02:12:24Z | - |
dc.date.issued | 2008 | * |
dc.identifier.issn | 0022-4596 | * |
dc.identifier.other | OAK-5049 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/233007 | - |
dc.description.abstract | We found new synthetic routes to obtain 1-D quaternary thiophosphate compounds and a 0-D molecular complex containing a Nb2S4 core from a 2-D ternary thiophosphate, Nb4P2S21. When Nb4P2S21 was reacted with alkali metal halides (ACl; A=Na, K, Rb, Cs) or TlCl at 500-700 °C, the -S-S-S- bridges in 2-D Nb2PS10-S-S10PNb2 were excised to form a 1-D chain, and cations were inserted between the chains to form ANb2PS10 (A=Na, K, Rb, Cs, Tl). We also found that thallium chloride (TlCl) is an excellent reagent for further excision, and it substitutes chloride ligands for the sulfur ligands of 2-D Nb4P2S21 to form the molecular complex Tl5[Nb2S4Cl8]Cl. Crystal data for TlNb2PS10: monoclinic, Pn, a=6.9452(11) Å, b=7.3761(12) Å, 12.873(2) Å, β=104.472(3)°, and Z=2. Crystal data for Tl5[Nb2S4Cl8]Cl: orthorhombic, Immm, a=7.001(5) Å, b=9.509(7) Å, c=15.546(11) Å, and Z=2. © 2008 Elsevier Inc. All rights reserved. | * |
dc.language | English | * |
dc.title | Dimensional reductions from 2-D Nb4P2S21 to 1-D ANb2PS10 (A=Na, K, Rb, Cs, Tl) and to 0-D Tl5[Nb2S4Cl8]Cl using halide molten salts | * |
dc.type | Article | * |
dc.relation.issue | 8 | * |
dc.relation.volume | 181 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 1798 | * |
dc.relation.lastpage | 1802 | * |
dc.relation.journaltitle | Journal of Solid State Chemistry | * |
dc.identifier.doi | 10.1016/j.jssc.2008.03.040 | * |
dc.identifier.wosid | WOS:000259098000014 | * |
dc.identifier.scopusid | 2-s2.0-52649091762 | * |
dc.author.google | Bang H. | * |
dc.author.google | Kim Y. | * |
dc.author.google | Kim S. | * |
dc.author.google | Kim S.-J. | * |
dc.contributor.scopusid | 김성진(56812714700) | * |
dc.contributor.scopusid | 김영미(57207443602) | * |
dc.date.modifydate | 20240301081003 | * |