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Tight binding and fluorescent sensing of oxalate in water

Title
Tight binding and fluorescent sensing of oxalate in water
Authors
Tang L.Park J.Kim H.-J.Kim Y.Sung J.K.Chin J.Kwan M.K.
Ewha Authors
김성진김영미김관묵
SCOPUS Author ID
김성진scopus; 김영미scopus; 김관묵scopus
Issue Date
2008
Journal Title
Journal of the American Chemical Society
ISSN
0002-7863JCR Link
Citation
vol. 130, no. 38, pp. 12606 - 12607
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
A dinuclear copper complex that binds tightly and selectively to oxalate over other dicarboxylates like malonate, succinate, and glutarate has been developed. This receptor can be used for fluorescent detection of oxalate in water at physicological pH by chemosensing ensemble approach. Crystal structure of oxalate bound to the receptor together with molecular mechanics and DFT computations provide insights into the tight and selective binding of the anion by the receptor. Copyright © 2008 American Chemical Society.
DOI
10.1021/ja804753n
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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