Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김성진 | * |
dc.contributor.author | 김영미 | * |
dc.date.accessioned | 2016-11-30T02:11:30Z | - |
dc.date.available | 2016-11-30T02:11:30Z | - |
dc.date.issued | 2008 | * |
dc.identifier.issn | 0022-2860 | * |
dc.identifier.other | OAK-5228 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/232905 | - |
dc.description.abstract | [Zn(bispicam)2]2+ as a hydrogen-bond donor and three free halides (Cl-, Br- and I-) as hydrogen-bond acceptors were employed to investigate the role of non-classical C/N-H⋯X hydrogen bonding for construction of polymeric compounds. Three zinc salts (ZnCl2, ZnBr2 and ZnI2) were reacted with bis(2-pyridylmethyl)amine (bispicam) to produce [Zn(bispicam)2]Cl2 1, [Zn(bispicam)2]Br2 2 and [Zn(bispicam)2]I2 3. Hydrogen bonding interactions between Namine-H and C-H of [Zn(bispicam)2]2+ cations and free halides, and between Owater-H and free halides can play very important roles for construction of molecular packing and crystal structures. In addition, these hydrogen-bonded complexes 1, 2 and 3 were, interestingly, shown to carry out the catalytic transesterification of a range of esters with methanol at 50 °C under the mild conditions, though all these compounds are saturated with two bispicam ligands. To explain this unusual reactivity, it has been proposed that the hydrogen atom of amine N-H moiety in the complexes could do the acid-catalyzed transesterification. © 2008 Elsevier B.V. All rights reserved. | * |
dc.language | English | * |
dc.title | Zinc(II) polymeric compounds with a chelating ligand bis(2-pyridylmethyl)amine (bispicam) directed by intermolecular C/N/O-H⋯X (X = Cl, Br, I) interactions: Catalytic activities | * |
dc.type | Article | * |
dc.relation.issue | 41277 | * |
dc.relation.volume | 890 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 123 | * |
dc.relation.lastpage | 129 | * |
dc.relation.journaltitle | Journal of Molecular Structure | * |
dc.identifier.doi | 10.1016/j.molstruc.2008.03.052 | * |
dc.identifier.wosid | WOS:000261121100020 | * |
dc.identifier.scopusid | 2-s2.0-53849091673 | * |
dc.author.google | Park B.K. | * |
dc.author.google | Lee S.H. | * |
dc.author.google | Lee E.Y. | * |
dc.author.google | Kwak H. | * |
dc.author.google | Lee Y.M. | * |
dc.author.google | Lee Y.J. | * |
dc.author.google | Jun J.Y. | * |
dc.author.google | Kim C. | * |
dc.author.google | Kim S.-J. | * |
dc.author.google | Kim Y. | * |
dc.contributor.scopusid | 김성진(56812714700) | * |
dc.contributor.scopusid | 김영미(57207443602) | * |
dc.date.modifydate | 20240301081003 | * |