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Ionic complexes based on the cluster anion [Re12CS 17(CN)6]6- and Cu2+ complex cations

Title
Ionic complexes based on the cluster anion [Re12CS 17(CN)6]6- and Cu2+ complex cations
Authors
Mironov Yu.V.Kim S.-J.Fedorov V.E.
Ewha Authors
김성진
SCOPUS Author ID
김성진scopus
Issue Date
2008
Journal Title
Russian Chemical Bulletin
ISSN
1066-5285JCR Link
Citation
vol. 57, no. 11, pp. 2271 - 2274
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The reactions of the dodecanuclear cluster anion [Re12CS 17(CN)6]6- with ammoniacal solutions of the divalent copper salts, CuCl2 and Cu(en)2Cl2, were studied. Two new ionic compounds [Cu(NH3)5] 3[Re12CS17(CN)6]•8H 2O (1) and Cu(NH3)(en)2][Cu(NH 3)3(en)]2-[Re12CS 17(CN)6]•5H2O (2) were synthesized. The structures of both compounds were established by single-crystal X-ray diffraction. © 2008 Springer Science+Business Media, Inc.
DOI
10.1007/s11172-008-0319-x
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자연과학대학 > 화학·나노과학전공 > Journal papers
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