Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Shunichi Fukuzumi | * |
dc.contributor.author | Kei Okubo | * |
dc.date.accessioned | 2016-09-21T01:09:20Z | - |
dc.date.available | 2016-09-21T01:09:20Z | - |
dc.date.issued | 2016 | * |
dc.identifier.issn | 1861-4728 | * |
dc.identifier.issn | 1861-471X | * |
dc.identifier.other | OAK-19257 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/232279 | - |
dc.description.abstract | Photooxidation of alkanes by dioxygen occurred under visible light irradiation of 2,3-dichloro-5,6-dicyanop-benzoquinone (DDQ) which acts as a super photooxidant. Solvent-free hydroxylation of cyclohexane and alkanes is initiated by electron transfer from alkanes to the singlet and triplet excited states of DDQ to afford the corresponding radical cations and DDQ(center dot-), as revealed by femtosecond laser-induced transient absorption measurements. Alkane radical cations readily deprotonate to produce alkyl radicals, which react with dioxygen to afford alkylperoxyl radicals. Alkylperoxyl radicals abstract hydrogen atoms from alkanes to yield alkyl hydroperoxides, accompanied by regeneration of alkyl radicals to constitute the radical chain reactions, so called autoxidation. The radical chain is terminated in the bimolecular reactions of alkylperoxyl radicals to yield the corresponding alcohols and ketones. DDQ(center dot-), produced by the photoinduced electron transfer from alkanes to the excited state of DDQ, disproportionates with protons to yield DDQH(2). | * |
dc.language | English | * |
dc.publisher | WILEY-V C H VERLAG GMBH | * |
dc.subject | electron transfer | * |
dc.subject | oxygenation | * |
dc.subject | photoredox catalysis | * |
dc.subject | quinone | * |
dc.subject | radical | * |
dc.title | Solvent-Free Photooxidation of Alkanes by Dioxygen with 2,3-Dichloro-5,6-dicyano-p-benzoquinone via Photoinduced Electron Transfer | * |
dc.type | Article | * |
dc.relation.issue | 16 | * |
dc.relation.volume | 11 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 2255 | * |
dc.relation.lastpage | 2259 | * |
dc.relation.journaltitle | CHEMISTRY-AN ASIAN JOURNAL | * |
dc.identifier.doi | 10.1002/asia.201600828 | * |
dc.identifier.wosid | WOS:000383606700005 | * |
dc.identifier.scopusid | 2-s2.0-84983335848 | * |
dc.author.google | Ohkubo, Kei | * |
dc.author.google | Hirose, Kensaku | * |
dc.author.google | Fukuzumi, Shunichi | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.contributor.scopusid | Kei Okubo(7101788990) | * |
dc.date.modifydate | 20240802081000 | * |