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A dream combination for catalysis: Highly reactive and recyclable scandium(iii) triflate-catalyzed cyanosilylations of carbonyl compounds in an ionic liquid

Title
A dream combination for catalysis: Highly reactive and recyclable scandium(iii) triflate-catalyzed cyanosilylations of carbonyl compounds in an ionic liquid
Authors
Park B.Y.Ryu K.Y.Park J.H.Lee S.-G.
Ewha Authors
이상기
SCOPUS Author ID
이상기scopus
Issue Date
2009
Journal Title
Green Chemistry
ISSN
1463-9262JCR Link
Citation
vol. 11, no. 7, pp. 946 - 948
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The catalytic activity of lanthanide triflates, particularly scandium triflate, increased dramatically in [bmim][SbF6], allowing the cyanosilylation of a variety of aldehydes and ketones with a turnover frequency up to 48000 mol h-1 and a total turnover number of 100000. © 2009 The Royal Society of Chemistry.
DOI
10.1039/b900254e
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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