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Novel three-dimensional coordination polymers based on [Mo 6Se8(CN)6]7- anions and Mn 2+ Cations

Title
Novel three-dimensional coordination polymers based on [Mo 6Se8(CN)6]7- anions and Mn 2+ Cations
Authors
Brylev K.A.Naumov N.G.Virovets A.V.Kim S.-J.Fedorov V.E.
Ewha Authors
김성진
SCOPUS Author ID
김성진scopus
Issue Date
2009
Journal Title
Journal of Cluster Science
ISSN
1040-7278JCR Link
Citation
vol. 20, no. 1, pp. 165 - 176
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Three novel coordination polymers K5[MnMo6Se 8(CN)6] • 8H2O (1), (Me4N) 4[{Mn(H2O)2}1.5Mo6Se 8(CN)6] • 4H2O (2), and K 3[{Mn2(H2O)4}Mo6Se 8(CN)6] • 7H2O (3) have been synthesized by layering of a methanol solution of [Mn(salen)]CH3COO (salen-N,N′-bis(salicylidene)ethylenediamine) on an aqueous solution of K7[Mo6Se8(CN)6] • 8H 2O. The compounds have been characterized by single-crystal X-ray diffraction analysis. All structures are based on negatively charged porous polymer frameworks where CN groups of [Mo6Se8(CN) 6]7- cluster complexes are coordinated to Mn2+ cations. Cavities in the frameworks are filled by additional cations and solvate water molecules. © 2008 Springer Science+Business Media, LLC.
DOI
10.1007/s10876-008-0215-4
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자연과학대학 > 화학·나노과학전공 > Journal papers
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