Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Shunichi Fukuzumi | * |
dc.contributor.author | Kei Okubo | * |
dc.date.accessioned | 2016-08-29T12:08:48Z | - |
dc.date.available | 2016-08-29T12:08:48Z | - |
dc.date.issued | 2017 | * |
dc.identifier.issn | 0894-3230 | * |
dc.identifier.issn | 1099-1395 | * |
dc.identifier.other | OAK-19179 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/231828 | - |
dc.description.abstract | Dihydroxylation of styrene by chlorite (ClO2-) with scandium triflate [Sc(OTf)(3)] occurs efficiently to produce 1-phenylethane-1,2-diol under the ambient conditions. Scandium triflate acting as a strong Lewis acid is found to accelerate the disproportionation of ClO2- to produce ClO- and ClO3-. A scandium-chlorine dioxide complex ((Sc3+ClO2 center dot)) is generated by the reaction of ClO- with ClO2- in the presence of Sc3+. The binding of Sc3+ to ClO2 center dot was detected by the electron paramagnetic resonance measurements, enhancing the reactivity and selectivity of styrene hydroxylation. | * |
dc.language | English | * |
dc.publisher | WILEY | * |
dc.subject | chlorine dioxide | * |
dc.subject | chlorite | * |
dc.subject | dihydroxylation | * |
dc.subject | electron paramagnetic resonance | * |
dc.subject | Lewis acid | * |
dc.title | Dihydroxylation of styrene by sodium chlorite with scandium triflate | * |
dc.type | Article | * |
dc.relation.issue | 5 | * |
dc.relation.volume | 30 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.journaltitle | JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | * |
dc.identifier.doi | 10.1002/poc.3619 | * |
dc.identifier.wosid | WOS:000398853200003 | * |
dc.identifier.scopusid | 2-s2.0-84980371769 | * |
dc.author.google | Ohkubo, Kei | * |
dc.author.google | Hirose, Kensaku | * |
dc.author.google | Shibata, Takekatsu | * |
dc.author.google | Takamori, Kiyoto | * |
dc.author.google | Fukuzumi, Shunichi | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.contributor.scopusid | Kei Okubo(7101788990) | * |
dc.date.modifydate | 20240401081001 | * |