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Structure of poly[diaqua[μ-1,2-bis(pyridin-4-yl)ethane-κ2N:N']bis(μ3-cyclobutane-1,1-dicarboxylato-κ3O,O':O':-O″')dimanganese(II)]

Title
Structure of poly[diaqua[μ-1,2-bis(pyridin-4-yl)ethane-κ2N:N']bis(μ3-cyclobutane-1,1-dicarboxylato-κ3O,O':O':-O″')dimanganese(II)]
Authors
Lee D.N.Kim Y.
Ewha Authors
김영미
SCOPUS Author ID
김영미scopus
Issue Date
2015
Journal Title
Acta Crystallographica Section E: Crystallographic Communications
ISSN
2056-9890JCR Link
Citation
vol. 71, pp. m150 - m151
Keywords
Crystal structureCyclobutane-1,1-dicarboxylate (cbdc) ligandManganese(II)α,ω-alkanedicarboxylate
Publisher
International Union of Crystallography
Indexed
SCOPUS scopus
Abstract
In the title compound, [Mn(C6H6O4)(C12H12N2)(H2O)]n, the cyclobutane-1,1-dicarboxylate (cbdc) ligands bridge three MnII ions, forming layers parallel to the ac plane. These layers are additionally connected by 1,2-bis(pyridin-4-yl)ethane ligands to form a three-dimensional polymeric framework. An inversion centre is located at the mid-point of the central C-C bond of the 1,2-bis(pyridin-4-yl)ethane ligand. The coordination geometry of the MnII ion is distorted octahedral and is built up by four carboxylate O atoms, one water O atom and a pyridyl N atom. The pyridine ligand and the coordinating water molecule are in a trans configuration. One carboxylate group of the cbdc ligand acts as a chelating ligand towards one MnII atom, whereas the second carboxylate group coordinates two different MnII atoms.
DOI
10.1107/S2056989015013791
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자연과학대학 > 화학·나노과학전공 > Journal papers
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Structure of poly[diaqua[μ-1,2-bis(pyridin-4-yl)ethane-κ2NN']bis(μ3-cyclobutane-1,1-dicarboxylato-κ3O,O'O'-O″')dimanganese(II)].pdf(577.16 kB)Download
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