Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | 이용민 | * |
dc.contributor.author | 서미숙 | * |
dc.contributor.author | 김원석 | * |
dc.date.accessioned | 2016-08-29T12:08:57Z | - |
dc.date.available | 2016-08-29T12:08:57Z | - |
dc.date.issued | 2016 | * |
dc.identifier.issn | 1433-7851 | * |
dc.identifier.issn | 1521-3773 | * |
dc.identifier.other | OAK-18850 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/231659 | - |
dc.description.abstract | Mononuclear nonheme high-spin (S=2) iron(IV)oxo species have been identified as the key intermediates responsible for the C-H bond activation of organic substrates in nonheme iron enzymatic reactions. Herein we report that the C-H bond activation of hydrocarbons by a synthetic mononuclear nonheme high-spin (S=2) iron(IV)-oxo complex occurs through an oxygen non-rebound mechanism, as previously demonstrated in the C-H bond activation by nonheme intermediate (S=1) iron(IV)-oxo complexes. We also report that C-H bond activation is preferred over C=C epoxidation in the oxidation of cyclohexene by the nonheme high-spin (HS) and intermediate-spin (IS) iron(IV)-oxo complexes, whereas the C=C double bond epoxidation becomes a preferred pathway in the oxidation of deuterated cyclohexene by the nonheme HS and IS iron(IV)-oxo complexes. In the epoxidation of styrene derivatives, the HS and IS iron(IV) oxo complexes are found to have similar electrophilic characters. | * |
dc.language | English | * |
dc.publisher | WILEY-V C H VERLAG GMBH | * |
dc.subject | bioinorganic chemistry | * |
dc.subject | C-H activation | * |
dc.subject | iron | * |
dc.subject | metalloenzymes | * |
dc.subject | reaction mechanisms | * |
dc.title | Mononuclear Nonheme High-Spin (S=2) versus Intermediate-Spin (S=1) Iron(IV)-Oxo Complexes in Oxidation Reactions | * |
dc.type | Article | * |
dc.relation.issue | 28 | * |
dc.relation.volume | 55 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 8027 | * |
dc.relation.lastpage | 8031 | * |
dc.relation.journaltitle | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | * |
dc.identifier.doi | 10.1002/anie.201603978 | * |
dc.identifier.wosid | WOS:000383253100024 | * |
dc.identifier.scopusid | 2-s2.0-84973550004 | * |
dc.author.google | Bae, Seong Hee | * |
dc.author.google | Seo, Mi Sook | * |
dc.author.google | Lee, Yong-Min | * |
dc.author.google | Cho, Kyung-Bin | * |
dc.author.google | Kim, Won-Suk | * |
dc.author.google | Nam, Wonwoo | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | 이용민(36546331100;35233855500;57192113229) | * |
dc.contributor.scopusid | 서미숙(7101805112) | * |
dc.contributor.scopusid | 김원석(57203484044) | * |
dc.date.modifydate | 20240426135715 | * |