Full metadata record
DC Field | Value | Language |
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dc.contributor.author | 황성주 | - |
dc.date.accessioned | 2016-08-29T12:08:50Z | - |
dc.date.available | 2016-08-29T12:08:50Z | - |
dc.date.issued | 2016 | - |
dc.identifier.issn | 1932-7447 | - |
dc.identifier.other | OAK-18673 | - |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/231571 | - |
dc.description.abstract | A rapid synthetic route to nanocrystalline carbon-incorporated mixed metal oxide nanocomposites with enhanced electrode performance for lithium ion batteries is developed by applying a very short heat-treatment of layered double hydroxide (LDH) precursor under C2H2 flow. Employing C2H2 atmosphere makes possible the rapid synthesis of nanocrystalline C-NiO-NiFe2O4 nanocomposite via the calcination of the Ni-Fe-LDH precursor at 300 °C in a very short period of 5 min. In the case of ambient atmosphere, a prolonged calcination time of several hours is demanded to induce a complete phase transformation from Ni-Fe-LDH to electrochemically active NiO-NiFe2O4 nanocomposite, highlighting the usefulness of C2H2 atmosphere in promoting the formation of mixed metal oxide nanocomposite. The present C-NiO-NiFe2O4 nanocomposite shows much better anode performance for lithium ion batteries with greater discharge capacity and better cyclability than do the NiO-NiFe2O4 nanocomposites prepared by the prolonged calcination of LDH under ambient atmosphere. The superior electrode activity of the present C-NiO-NiFe2O4 nanocomposite is attributable to the optimization of charge transfer induced by the enhanced electrical conductivity and a short diffusion length of Li ion. The present C2H2-assisted phase transition of LDH precursor provides a convenient, economic, and scalable synthetic way to carbon-mixed metal oxide nanocomposites with promising electrode performance for lithium ion batteries. © 2016 American Chemical Society. | - |
dc.language | English | - |
dc.publisher | American Chemical Society | - |
dc.title | Rapid Synthetic Route to Nanocrystalline Carbon-Mixed Metal Oxide Nanocomposites with Enhanced Electrode Functionality | - |
dc.type | Article | - |
dc.relation.issue | 16 | - |
dc.relation.volume | 120 | - |
dc.relation.index | SCIE | - |
dc.relation.index | SCOPUS | - |
dc.relation.startpage | 8451 | - |
dc.relation.lastpage | 8460 | - |
dc.relation.journaltitle | Journal of Physical Chemistry C | - |
dc.identifier.doi | 10.1021/acs.jpcc.6b00841 | - |
dc.identifier.wosid | WOS:000375521700005 | - |
dc.identifier.scopusid | 2-s2.0-84966335516 | - |
dc.author.google | Lee J.M. | - |
dc.author.google | Gu T.H. | - |
dc.author.google | Kwon N.H. | - |
dc.author.google | Oh S.M. | - |
dc.author.google | Hwang S.-J. | - |
dc.contributor.scopusid | 황성주(7404626171) | - |
dc.date.modifydate | 20190901081003 | - |