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Photocatalytic oxidation of iron(II) complexes by dioxygen using 9-mesityl-10-methylacridinium ions

Title
Photocatalytic oxidation of iron(II) complexes by dioxygen using 9-mesityl-10-methylacridinium ions
Authors
Tsudaka T.Ohkubo K.Fukuzumi S.
Ewha Authors
Shunichi FukuzumiKei Okubo
SCOPUS Author ID
Shunichi Fukuzumiscopus; Kei Okuboscopus
Issue Date
2016
Journal Title
Chemical Communications
ISSN
1359-7345JCR Link
Citation
vol. 52, no. 36, pp. 6178 - 6180
Publisher
Royal Society of Chemistry
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Photocatalytic oxidation of iron(ii) complexes by dioxygen occurred using the organic photocatalysts, 9-mesityl-10-methylacridinium ions (Acr+-Mes) and 2-phenyl-4-(1-naphthyl) quinolinium ions (QuPh+-NA), in the presence of triflic acid in acetonitrile under visible light irradiation. The electron-transfer state of Acr+-Mes produced upon photoexcitation oxidized the iron(ii) complexes, whereas it reduced dioxygen with protons to produce iron(iii) complexes and H2O2. © 2016 The Royal Society of Chemistry.
DOI
10.1039/c6cc00359a
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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