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Two-phase oxidation of toluene derivatives by dioxygen using the 3-cyano-1-decylquinolinium ion as a photocatalyst

Title
Two-phase oxidation of toluene derivatives by dioxygen using the 3-cyano-1-decylquinolinium ion as a photocatalyst
Authors
Ohkubo K.Hirose K.Fukuzumi S.
Ewha Authors
Shunichi FukuzumiKei Okubo
SCOPUS Author ID
Shunichi Fukuzumiscopus; Kei Okuboscopus
Issue Date
2016
Journal Title
RSC Advances
ISSN
2046-2069JCR Link
Citation
vol. 6, no. 47, pp. 41011 - 41014
Publisher
Royal Society of Chemistry
Indexed
SCIE; SCOPUS WOS scopus
Abstract
The two-phase photocatalytic oxidation of toluene and p-xylene by dioxygen occurred efficiently using 3-cyano-1-decylquinolinium hexafluorophosphate (DeQuCN+PF6 -) as an organic photocatalyst. When toluene and p-xylene were used as the solvent with 2% H2O, the oxygenated products were produced in the organic phase and hydrogen peroxide was produced in the aqueous phase at high turnover numbers. © The Royal Society of Chemistry 2016.
DOI
10.1039/c6ra05993g
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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