Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Shunichi Fukuzumi | * |
dc.date.accessioned | 2016-08-29T12:08:00Z | - |
dc.date.available | 2016-08-29T12:08:00Z | - |
dc.date.issued | 2015 | * |
dc.identifier.issn | 2040-3364 | * |
dc.identifier.other | OAK-14782 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/230519 | - |
dc.description.abstract | The first perylenediimide (PDI) covalently linked to an azafullerene (C<inf>59</inf>N) is described. PDI-C<inf>59</inf>N and PDI-C<inf>60</inf> dyads where PDI acts as an electron-donor moiety have been synthesized by connection of the balls to the PDI 1-bay position. Photoexcitation of the PDI unit in both systems results in formation of the charge-separated state by photoinduced electron transfer from the singlet excited state of the PDI moiety to the C<inf>59</inf>N or to the C<inf>60</inf> moiety. The charge-separated state has a lifetime of 400 ps in the case of PDI-C<inf>59</inf>N and 120 ps for the PDI-C<inf>60</inf> dyad in benzonitrile at 298 K. This result has significant implications for the design of organic solar cells based on covalent donor-acceptor systems using C<inf>59</inf>N as an electron acceptor, indicating that longer-lived charge-separated states can be attained using C<inf>59</inf>N systems instead of C<inf>60</inf> systems. © 2015 The Royal Society of Chemistry. | * |
dc.language | English | * |
dc.publisher | Royal Society of Chemistry | * |
dc.title | Does a nitrogen matter? Synthesis and photoinduced electron transfer of perylenediimide donors covalently linked to C<inf>59</inf>N and C<inf>60</inf> acceptors | * |
dc.type | Article | * |
dc.relation.issue | 16 | * |
dc.relation.volume | 7 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 7437 | * |
dc.relation.lastpage | 7444 | * |
dc.relation.journaltitle | Nanoscale | * |
dc.identifier.doi | 10.1039/c5nr00308c | * |
dc.identifier.wosid | WOS:000352905700063 | * |
dc.identifier.scopusid | 2-s2.0-84927949226 | * |
dc.author.google | Martin-Gomis L. | * |
dc.author.google | Rotas G. | * |
dc.author.google | Ohkubo K. | * |
dc.author.google | Fernandez-Lazaro F. | * |
dc.author.google | Fukuzumi S. | * |
dc.author.google | Tagmatarchis N. | * |
dc.author.google | Sastre-Santos A. | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.date.modifydate | 20240401081001 | * |