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Anionic 1,2,3-triazole-4,5-diylidene: A 1,2-dihapto ligand for the construction of bimetallic complexes

Title
Anionic 1,2,3-triazole-4,5-diylidene: A 1,2-dihapto ligand for the construction of bimetallic complexes
Authors
Yan X.Bouffard J.Guisado-Barrios G.Donnadieu B.Bertrand G.
Ewha Authors
Jean Bouffard
SCOPUS Author ID
Jean Bouffardscopus
Issue Date
2012
Journal Title
Chemistry - A European Journal
ISSN
0947-6539JCR Link
Citation
vol. 18, no. 46, pp. 14627 - 14631
Indexed
SCI; SCIE; SCOPUS scopus
Abstract
A super pyrazolate: Deprotonation of the flanking hydrogen of metal complexes of mesoionic carbenes (MICs) offers a simple and general route for the preparation of bimetallic complexes of a 1,2-dihapto anionic dicarbene ligand that is isoelectronic with widely used pyrazolate ligands, while conferring greater electron donation and stronger M-L bonds (see scheme). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
DOI
10.1002/chem.201202862
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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