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Bis(-2-carboxymethyl-2-hydroxy-butane-dioato)bis-[diaqua-manganese(II)]-1, 2-bis-(pyridin-4-yl)ethane-water (1/1/2)

Title
Bis(-2-carboxymethyl-2-hydroxy-butane-dioato)bis-[diaqua-manganese(II)]-1, 2-bis-(pyridin-4-yl)ethane-water (1/1/2)
Authors
Hwang I.H.Kim P.-G.Kim C.Kim Y.
Ewha Authors
김영미
SCOPUS Author ID
김영미scopus
Issue Date
2012
Journal Title
Acta Crystallographica Section E: Structure Reports Online
ISSN
1600-5368JCR Link
Citation
vol. 68, no. 8, pp. m1116 - m1117
Indexed
SCOPUS scopus
Abstract
The asymmetric unit of the title compound, [Mn2(C 6H6O7)2(H2O) 4]·C12H12N2· 2H2O, comprises half of a centrosymmetric dimer, half of a 1,2-bis-(pyridin-4-yl)ethane and one water mol-ecule. Two citrate ligands bridge two MnII ions, the MnII ion being coordinated by four O atoms from the citrate(2-) ligands and two water O atoms, forming a distorted octa-hedral environment. In the crystal, O-H⋯O hydrogen bonds link the centrosymmetric dimers and lattice water mol-ecules into a three-dimensional structure which is further stabilized by inter-molecular π-π inter-actions [centroid-centroid distance = 3.792 (2) Å].
DOI
10.1107/S1600536812032771
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자연과학대학 > 화학·나노과학전공 > Journal papers
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