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Preparation and reactivity of a nickel dihydride complex

Title
Preparation and reactivity of a nickel dihydride complex
Authors
Matsumoto T.Nagahama T.Cho J.Hizume T.Suzuki M.Ogo S.
Ewha Authors
조재흥
Issue Date
2011
Journal Title
Angewandte Chemie - International Edition
ISSN
1433-7851JCR Link
Citation
vol. 50, no. 45, pp. 10578 - 10580
Indexed
SCI; SCIE; SCOPUS scopus
Abstract
A generous donor: A dinuclear octahedral bis(μ-hydrido)dinickel(II) complex (see picture; C gray, H black, N blue, Ni green) acts as an electron donor to reduce electron acceptors such as methyl viologen. The complex is proposed as a functional model for the dihydride intermediate of an NiRu hydrogenase mimic and, by extension, of [NiFe]hydrogenase itself. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
DOI
10.1002/anie.201104918
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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