Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김성진 | * |
dc.contributor.author | 남원우 | * |
dc.contributor.author | 김영미 | * |
dc.contributor.author | 서미숙 | * |
dc.date.accessioned | 2016-08-28T11:08:09Z | - |
dc.date.available | 2016-08-28T11:08:09Z | - |
dc.date.issued | 2009 | * |
dc.identifier.issn | 0253-2964 | * |
dc.identifier.other | OAK-13348 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/229358 | - |
dc.description.abstract | Utilizing a planar five coordinating N3S2 ligand, 2,6-bis(2-methylthiophenyliminomethyl)pyridine, a pseudo 7-coordinated manganese(II) complex with two labile triflate anions in the axial positions was synthesized. The reaction of the manganese(I oI) complex with an oxidant, iodosylbenzene, produced a metastable high-valent manganese(IV)-oxo species at 0 °C. The high-valent Mn(IV)-oxo intermediate was characterized with a UV-vis spectrophotometer and an electrospray ionization mass spectroscopy. Reactivity studies of the Mn(IV)=O species revealed that the intermediate is capable of oxygenating PPh3 and N-dealkylating N, N-dimethyl-toludine. | * |
dc.language | English | * |
dc.title | Synthesis and reactivity of a mononuclear manganese (II) complex having pseudo-seven coordination environment | * |
dc.type | Article | * |
dc.relation.issue | 3 | * |
dc.relation.volume | 30 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.index | KCI | * |
dc.relation.startpage | 679 | * |
dc.relation.lastpage | 682 | * |
dc.relation.journaltitle | Bulletin of the Korean Chemical Society | * |
dc.identifier.doi | 10.5012/bkcs.2009.30.3.679 | * |
dc.identifier.wosid | WOS:000265240000029 | * |
dc.identifier.scopusid | 2-s2.0-73249137747 | * |
dc.author.google | Yoon J. | * |
dc.author.google | Seo M.S. | * |
dc.author.google | Kim Y. | * |
dc.author.google | Kim S.-J. | * |
dc.author.google | Yoon S. | * |
dc.author.google | Jang H.G. | * |
dc.author.google | Nam W. | * |
dc.contributor.scopusid | 김성진(56812714700) | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | 김영미(57207443602) | * |
dc.date.modifydate | 20240301081003 | * |