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Solandelactones A-I, lactonized cyclopropyl oxylipins isolated from the hydroid Solanderia secunda

Title
Solandelactones A-I, lactonized cyclopropyl oxylipins isolated from the hydroid Solanderia secunda
Authors
Seo Y.Cho K.W.Rho J.-R.Shin J.Kwon B.-M.Bok S.-H.Song J.-I.
Ewha Authors
송준임
SCOPUS Author ID
송준임scopus
Issue Date
1996
Journal Title
Tetrahedron
ISSN
0040-4020JCR Link
Citation
Tetrahedron vol. 52, no. 32, pp. 10583 - 10596
Indexed
SCI; SCIE; SCOPUS scopus
Document Type
Article
Abstract
Solandelactones A-I(1-9), cyclopropyl and lactone containing novel docosanoids have been isolated from the hydroid Solanderia secunda. The structure of these compounds have been elucidated by combined spectral and chemical studies. Configuration of the cyclopropyl ring has been essigned as the opposite of related oxylipins by NOESY experiments. Absolute stereochemistry has been determined on the basis of chemical transformations and CD measurements of synthetic derivatives. In addition, the biogenetic origin of solandelactones has been discussed. Solandelactones C, D and G exhibited moderate inhibitory activity against Farnesyl Protein Transferase.
DOI
10.1016/0040-4020(96)00606-0
Appears in Collections:
자연과학대학 > 생명과학전공 > Journal papers
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