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Solvent effect on rate for anionic nucleophilic substitution reaction of 4-nitrophenyl acetate in aqueous acetonitrile

Title
Solvent effect on rate for anionic nucleophilic substitution reaction of 4-nitrophenyl acetate in aqueous acetonitrile
Authors
Um I.-H.Lee G.-J.Yoon H.-W.Kwon D.-S.
Ewha Authors
권동숙엄익환
SCOPUS Author ID
권동숙scopusscopus; 엄익환scopusscopus
Issue Date
1992
Journal Title
Tetrahedron Letters
ISSN
0040-4039JCR Link
Citation
vol. 33, no. 15, pp. 2023 - 2026
Indexed
SCI; SCIE; SCOPUS scopus
Abstract
Second order rate constants have been measured for anionic nucleophilic substitution reactions of 4-nitrophenyl acetate in MeCN-H2O mixtures. The results show rate minima near 30-40 mole % MeCN, which are attributed to changes in solvent structure.
DOI
10.1016/0040-4039(92)88130-W
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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