Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 양인상 | - |
dc.date.accessioned | 2016-08-28T10:08:14Z | - |
dc.date.available | 2016-08-28T10:08:14Z | - |
dc.date.issued | 2013 | - |
dc.identifier.issn | 0374-4884 | - |
dc.identifier.other | OAK-10283 | - |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/223888 | - |
dc.description.abstract | The electronic structures of Prussian blue analogue ACo[Fe(CN)6]H2O (A=Na, K) nano-size particles has been investigated by employing soft X-ray absorption spectroscopy (XAS) at the Fe and Co L edges. Both Fe and Co ions are found to be Fe2+-Fe3+ and Co2+-Co3+ mixed-valent, with the average valence of v(Fe)∼ 2.36 and v(Co)∼ 2.41. This finding suggests that the mechanism of the photo-induced spin transition in ACo[Fe(CN)6]H2O (A=Na, K) is not a simple spin-state transition of Fe2+-Co3+ → Fe3+-Co2+. The Fe ions in ACo[Fe(CN)6]H2O are also found to have a strong covalent bonding to (CN)- ligands, but a very weak bonding to O(H2O), while Co ions have a stronger bonding to O(H2O) than to (CN)- ligands. © 2013 The Korean Physical Society. | - |
dc.language | English | - |
dc.title | Soft x-ray absorption spectroscopy study of Prussian blue analogue ACo[Fe(CN)6]H2O nano-particles (A=Na, K) | - |
dc.type | Article | - |
dc.relation.issue | 12 | - |
dc.relation.volume | 62 | - |
dc.relation.index | SCI | - |
dc.relation.index | SCIE | - |
dc.relation.index | SCOPUS | - |
dc.relation.index | KCI | - |
dc.relation.startpage | 1910 | - |
dc.relation.lastpage | 1913 | - |
dc.relation.journaltitle | Journal of the Korean Physical Society | - |
dc.identifier.doi | 10.3938/jkps.62.1910 | - |
dc.identifier.wosid | WOS:000321590800044 | - |
dc.identifier.scopusid | 2-s2.0-84880009105 | - |
dc.author.google | Lee E. | - |
dc.author.google | Kim D.H. | - |
dc.author.google | Hwang J. | - |
dc.author.google | Kang J.-S. | - |
dc.author.google | Van Minh N. | - |
dc.author.google | Yang I.-S. | - |
dc.author.google | Ueno T. | - |
dc.author.google | Sawada M. | - |
dc.contributor.scopusid | 양인상(7101797839) | - |
dc.date.modifydate | 20230210140835 | - |