View : 19 Download: 0

Reactivity comparison of high-valent iron(iv)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size

Title
Reactivity comparison of high-valent iron(iv)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size
Authors
Hong S.So H.Yoon H.Cho K.-B.Lee Y.-M.Fukuzumi S.Nam W.
Ewha Authors
남원우Shunichi Fukuzumi이용민
SCOPUS Author ID
남원우scopus; Shunichi Fukuzumiscopus; 이용민scopusscopus
Issue Date
2013
Journal Title
Dalton Transactions
ISSN
1477-9226JCR Link
Citation
vol. 42, no. 22, pp. 7842 - 7845
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The ring size effect of macrocyclic TMC ligands in nonheme iron(iv)-oxo complexes has been examined in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; an iron(iv)-oxo complex bearing a smaller TMC ligand is more reactive in both HAT and OAT reactions, resulting from its high Fe IV/III redox potential. © 2013 The Royal Society of Chemistry.
DOI
10.1039/c3dt50750e
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

BROWSE