Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | 서미숙 | * |
dc.contributor.author | 이용민 | * |
dc.contributor.author | 박영준 | * |
dc.date.accessioned | 2016-08-28T10:08:55Z | - |
dc.date.available | 2016-08-28T10:08:55Z | - |
dc.date.issued | 2013 | * |
dc.identifier.issn | 0002-7863 | * |
dc.identifier.other | OAK-10060 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/223701 | - |
dc.description.abstract | Redox-inactive metal ions play pivotal roles in regulating the reactivities of high-valent metal-oxo species in a variety of enzymatic and chemical reactions. A mononuclear non-heme Mn(IV)-oxo complex bearing a pentadentate N5 ligand has been synthesized and used in the synthesis of a Mn(IV)-oxo complex binding scandium ions. The Mn(IV)-oxo complexes were characterized with various spectroscopic methods. The reactivities of the Mn(IV)-oxo complex are markedly influenced by binding of Sc3+ ions in oxidation reactions, such as a ∼2200-fold increase in the rate of oxidation of thioanisole (i.e., oxygen atom transfer) but a ∼180-fold decrease in the rate of C-H bond activation of 1,4-cyclohexadiene (i.e., hydrogen atom transfer). The present results provide the first example of a non-heme Mn(IV)-oxo complex binding redox-inactive metal ions that shows a contrasting effect of the redox-inactive metal ions on the reactivities of metal-oxo species in the oxygen atom transfer and hydrogen atom transfer reactions. © 2013 American Chemical Society. | * |
dc.language | English | * |
dc.title | A mononuclear non-heme manganese(IV)-oxo complex binding redox-inactive metal ions | * |
dc.type | Article | * |
dc.relation.issue | 17 | * |
dc.relation.volume | 135 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 6388 | * |
dc.relation.lastpage | 6391 | * |
dc.relation.journaltitle | Journal of the American Chemical Society | * |
dc.identifier.doi | 10.1021/ja312113p | * |
dc.identifier.wosid | WOS:000318469100003 | * |
dc.identifier.scopusid | 2-s2.0-84877084177 | * |
dc.author.google | Chen J. | * |
dc.author.google | Lee Y.-M. | * |
dc.author.google | Davis K.M. | * |
dc.author.google | Wu X. | * |
dc.author.google | Seo M.S. | * |
dc.author.google | Cho K.-B. | * |
dc.author.google | Yoon H. | * |
dc.author.google | Park Y.J. | * |
dc.author.google | Fukuzumi S. | * |
dc.author.google | Pushkar Y.N. | * |
dc.author.google | Nam W. | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | 이용민(36546331100;35233855500;57192113229) | * |
dc.contributor.scopusid | 박영준(57205877314) | * |
dc.date.modifydate | 20240426135715 | * |