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Functionalization of organotrifluoroborates via CU-catalyzed C-N coupling reaction

Title
Functionalization of organotrifluoroborates via CU-catalyzed C-N coupling reaction
Authors
Lee J.-H.Kim H.Kim T.Song J.H.Kim W.-S.Ham J.
Ewha Authors
김원석
SCOPUS Author ID
김원석scopus
Issue Date
2013
Journal Title
Bulletin of the Korean Chemical Society
ISSN
0253-2964JCR Link
Citation
Bulletin of the Korean Chemical Society vol. 34, no. 1, pp. 42 - 48
Indexed
SCI; SCIE; SCOPUS; KCI WOS scopus
Document Type
Article
Abstract
Potassium N-heterobiaryltrifluoroborates were successfully prepared via a selective Cu-catalyzed C-N coupling reaction. The BF3K moiety was well tolerated under the reaction conditions involving CuI and dimethylethylenediamine (DMEDA) in the presence of DMSO. The Pd-catalyzed Suzuki-Miyaura cross couplings of potassium N-heterobiaryltrifluoroborates with bromoarenes were studied to prepare the N-heterotriaryl compounds. Moreover, homocoupling, iodination, and hydroxylation of potassium N-heterobiaryltrifluoroborates provided the corresponding products in high yields.
DOI
10.5012/bkcs.2013.34.1.42
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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