View : 51 Download: 0

Copper complexes of the non-innocent β-diketiminate ligand containing phenol groups

Title
Copper complexes of the non-innocent β-diketiminate ligand containing phenol groups
Authors
Takaichi J.Ohkubo K.Sugimoto H.Nakano M.Usa D.Maekawa H.Fujieda N.Nishiwaki N.Seki S.Fukuzumi S.Itoh S.
Ewha Authors
Shunichi Fukuzumi
SCOPUS Author ID
Shunichi Fukuzumiscopus
Issue Date
2013
Journal Title
Dalton Transactions
ISSN
1477-9226JCR Link
Citation
vol. 42, no. 7, pp. 2438 - 2444
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
A new type of non-innocent β-diketiminate ligand having redox active phenol groups (LH3, fully protonated form) has been developed, and the structure, physical properties and reactivity of the supported copper(ii) complex [CuII(L3-)]- (L3-, fully deprotonated tri-anionic form) as well as the one-electron and two-electron oxidised complexes, [CuII(L̇2-)] and [Cu II(L-)]+, have been examined in detail. The two-electron oxidised form [CuII(L-)]+ exhibited hydrogen atom abstraction ability from 1,4-cyclohexadiene (CHD), whereas the one-electron oxidised form CuII(L̇2-)] was found to disproportionate into [CuII(L3-)]- and [CuII(L-)]+ during the course of the reaction with CHD. © 2013 The Royal Society of Chemistry.
DOI
10.1039/c2dt32413j
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

BROWSE