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Photocatalytic oxidation of organic compounds in water by using ruthenium(II)-pyridylamine complexes as catalysts with high efficiency and selectivity

Title
Photocatalytic oxidation of organic compounds in water by using ruthenium(II)-pyridylamine complexes as catalysts with high efficiency and selectivity
Authors
Ohzu S.Ishizuka T.Hirai Y.Fukuzumi S.Kojima T.
Ewha Authors
Shunichi Fukuzumi
SCOPUS Author ID
Shunichi Fukuzumiscopus
Issue Date
2013
Journal Title
Chemistry - A European Journal
ISSN
0947-6539JCR Link
Citation
vol. 19, no. 5, pp. 1563 - 1567
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The photocatalytic oxidation of organic substrates such as alcohols was conducted in the presence of RuII-aqua complexes as oxidation catalysts, [RuII(bpy)3]2+ as a photosensitizer and electron mediator, and a CoIII complex as a sacrificial oxidant (see scheme). The catalytic systems exhibited high efficiency to achieve turnover numbers of over 8000. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
DOI
10.1002/chem.201203430
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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