Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Shunichi Fukuzumi | * |
dc.contributor.author | Kenneth D. Karlin | * |
dc.date.accessioned | 2016-08-28T10:08:15Z | - |
dc.date.available | 2016-08-28T10:08:15Z | - |
dc.date.issued | 2013 | * |
dc.identifier.issn | 0010-8545 | * |
dc.identifier.other | OAK-9612 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/223311 | - |
dc.description.abstract | The kinetics and thermodynamics of formation of Cu(II)-superoxo (Cu-O 2) complexes by the reaction of Cu(I) complexes with dioxygen (O 2) and the reduction of Cu(II)-superoxo complexes to dinuclear Cu-peroxo complexes are discussed. In the former case, electron transfer from a Cu(I) complex to O 2 occurs concomitantly with binding of O 2 -to the corresponding Cu(II) species. This is defined as an inner-sphere Cu(II) ion-coupled electron transfer process. Electron transfer from another Cu(I) complex to preformed Cu(II)-superoxo complexes also occurs concomitantly with binding of the Cu(II)-peroxo species with the Cu(II) species to produce the dinuclear Cu-peroxo (Cu 2-O 2) complexes. The kinetics and thermodynamics of outer-sphere electron-transfer reduction of Cu 2-O 2 complexes are also been discussed in light of the Marcus theory of outer-sphere electron transfer. © 2012 Elsevier B.V.. | * |
dc.language | English | * |
dc.title | Kinetics and thermodynamics of formation and electron-transfer reactions of Cu-O 2 and Cu 2-O 2 complexes | * |
dc.type | Review | * |
dc.relation.issue | 1 | * |
dc.relation.volume | 257 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 187 | * |
dc.relation.lastpage | 195 | * |
dc.relation.journaltitle | Coordination Chemistry Reviews | * |
dc.identifier.doi | 10.1016/j.ccr.2012.05.031 | * |
dc.identifier.wosid | WOS:000312972700015 | * |
dc.identifier.scopusid | 2-s2.0-84870392949 | * |
dc.author.google | Fukuzumi S. | * |
dc.author.google | Karlin K.D. | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.date.modifydate | 20240401081001 | * |