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Cu(OAc)2-catalyzed tandem Blaise/Pinner-type reaction for one-pot synthesis of pyrimidin-4-ones

Title
Cu(OAc)2-catalyzed tandem Blaise/Pinner-type reaction for one-pot synthesis of pyrimidin-4-ones
Authors
Chun Y.S.Kim J.H.Choi S.Y.Ko Y.O.Lee S.-G.
Ewha Authors
이상기김주현
SCOPUS Author ID
이상기scopus
Issue Date
2012
Journal Title
Organic Letters
ISSN
1523-7060JCR Link
Citation
vol. 14, no. 24, pp. 6358 - 6361
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
A novel tandem Blaise/Pinner-type reaction for the one-pot synthesis of pyrimidin-4-ones is described. The Blaise reaction intermediate, formed by addition of a Reformatsky reagent to a nitrile, reacted with a second nitrile chemoselectively in the presence of a catalytic amount of Cu(OAc)2 to afford pyrimidin-4-ones. © 2012 American Chemical Society.
DOI
10.1021/ol303153g
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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