NL repository
menu
검색
Library
Browse
Communities & Collections
By Date
Authors
Titles
Subject
My Repository
My Account
Receive email updates
Edit Profile
DSpace at EWHA
자연과학대학
화학·나노과학전공
Journal papers
View : 652 Download: 0
Receptor that can capture a discrete monohydrated fluoride anion
Title
Receptor that can capture a discrete monohydrated fluoride anion
Authors
Sokkalingam P.
;
Kee S.-Y.
;
Kim Y.
;
Kim S.-J.
;
Lee P.H.
;
Lee C.-H.
Ewha Authors
김성진
;
김영미
SCOPUS Author ID
김성진
; 김영미
Issue Date
2012
Journal Title
Organic Letters
ISSN
1523-7060
Citation
Organic Letters vol. 14, no. 24, pp. 6234 - 6237
Indexed
SCI; SCIE; SCOPUS
Document Type
Article
Abstract
A 'picket calix[4]pyrrole' bearing a well-defined binding domain has allowed the stabilization of a monohydrated fluoride anion. The monohydrated F- was observed only when CsF (not the TBAF) was treated with a host in aqueous acetonitrile. The structure of the receptor-bound, monohydrated F- was fully characterized by single crystal X-ray diffraction analysis as well as by low temperature 1H and 19F NMR spectroscopy. Further analysis revealed that the complex formed a three-dimensional, salt mediated organic framework in the solid state. © 2012 American Chemical Society.
DOI
10.1021/ol302996y
Appears in Collections:
자연과학대학
>
화학·나노과학전공
>
Journal papers
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML
Show full item record
Find@EWHA
트윗하기
BROWSE
Communities & Collections
By Date
Authors
Titles
Subject