Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Shunichi Fukuzumi | * |
dc.date.accessioned | 2016-08-28T12:08:29Z | - |
dc.date.available | 2016-08-28T12:08:29Z | - |
dc.date.issued | 2012 | * |
dc.identifier.issn | 0947-6539 | * |
dc.identifier.other | OAK-8860 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/222713 | - |
dc.description.abstract | Donor-bridge-acceptor triad (Por-2TV-C 60) and tetrad molecules ((Por) 2-2TV-C 60), which incorporated C 60 and one or two porphyrin molecules that were covalently linked through a phenylethynyl-oligothienylenevinylene bridge, were synthesized. Their photodynamics were investigated by fluorescence measurements, and by femto- and nanosecond laser flash photolysis. First, photoinduced energy transfer from the porphyrin to the C 60 moiety occurred rather than electron transfer, followed by electron transfer from the oligothienylenevinylene to the singlet excited state of the C 60 moiety to produce the radical cation of oligothienylenevinylene and the radical anion of C 60. Then, back-electron transfer occurred to afford the triplet excited state of the oligothienylenevinylene moiety rather than the ground state. Thus, the porphyrin units in (Por)-2TV-C 60 and (Por) 2-2TV-C 60 acted as efficient photosensitizers for the charge separation between oligothienylenevinylene and C 60. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | * |
dc.language | English | * |
dc.title | Photoinduced energy and electron transfer in phenylethynyl-bridged zinc porphyrin-oligothienylenevinylene-C 60 ensembles | * |
dc.type | Article | * |
dc.relation.issue | 24 | * |
dc.relation.volume | 18 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 7473 | * |
dc.relation.lastpage | 7485 | * |
dc.relation.journaltitle | Chemistry - A European Journal | * |
dc.identifier.doi | 10.1002/chem.201102260 | * |
dc.identifier.wosid | WOS:000304755700020 | * |
dc.identifier.scopusid | 2-s2.0-84861829874 | * |
dc.author.google | Urbani M. | * |
dc.author.google | Ohkubo K. | * |
dc.author.google | Islam D.M.S. | * |
dc.author.google | Fukuzumi S. | * |
dc.author.google | Langa F. | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.date.modifydate | 20240401081001 | * |