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dc.contributor.authorShunichi Fukuzumi-
dc.date.accessioned2017-08-28T23:04:04Z-
dc.date.available2017-08-28T23:04:04Z-
dc.date.issued2012-
dc.identifier.issn1754-5692-
dc.identifier.urihttp://dspace.ewha.ac.kr/handle/2015.oak/222677-
dc.description.abstractInterconversion between hydrogen and formic acid in water at ambient temperature and pressure has been made possible by using a [C,N] cyclometalated organoiridium complex, [IrIII(Cp*)(4-(1H-pyrazol-1-yl- κN2)benzoic acid-κC3)(H2O)] 2SO4 [1]2·SO4, as an efficient catalyst for both directions depending on pH. Hydrogenation of carbon dioxide by hydrogen occurs in the presence of a catalytic amount of 1 under an atmospheric pressure of H2 and CO2 in weakly basic water (pH 7.5) at room temperature, whereas formic acid efficiently decomposes to afford H2 and CO2 in the presence of 1 in acidic water (pH 2.8). This journal is © 2012 The Royal Society of Chemistry.-
dc.languageEnglish-
dc.titleCatalytic interconversion between hydrogen and formic acid at ambient temperature and pressure-
dc.typeArticle-
dc.relation.issue6-
dc.relation.volume5-
dc.relation.indexSCI-
dc.relation.indexSCIE-
dc.relation.indexSCOPUS-
dc.relation.startpage7360-
dc.relation.lastpage7367-
dc.relation.journaltitleEnergy and Environmental Science-
dc.identifier.doi10.1039/c2ee03315a-
dc.identifier.wosidWOS:000304354900010-
dc.identifier.scopusid2-s2.0-84863103742-
dc.author.googleMaenaka Y.-
dc.author.googleSuenobu T.-
dc.author.googleFukuzumi S.-
dc.contributor.scopusidShunichi Fukuzumi(35430038100)-
dc.date.modifydate20180517105308-
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자연과학대학 > 화학·나노과학전공 > Journal papers
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