View : 10 Download: 0

Solvothermal-assisted hybridization between reduced graphene oxide and lithium metal oxides: A facile route to graphene-based composite materials

Title
Solvothermal-assisted hybridization between reduced graphene oxide and lithium metal oxides: A facile route to graphene-based composite materials
Authors
Han S.Y.Kim I.Y.Jo K.Y.Hwang S.-J.
Ewha Authors
황성주
SCOPUS Author ID
황성주scopus
Issue Date
2012
Journal Title
Journal of Physical Chemistry C
ISSN
1932-7447JCR Link
Citation
vol. 116, no. 13, pp. 7269 - 7279
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Hybridization between lithium metal oxide and reduced graphene oxide, or RGO, can be achieved by the solvothermal treatment of the water/ethanol-based suspension of graphite oxide, or GO, nanosheets containing powdery lithium metal oxide. The solvothermal treatment for the mixture suspension of GO and Li 4Ti 5O 12 gives rise not only to the reduction of GO to RGO but also to the attachment of the Li 4Ti 5O 12 particles to the flat surface of RGO 2D nanosheets. The crystal structure and crystal morphology of the Li 4Ti 5O 12 particles remain intact after the composite formation with the RGO nanosheets. The formation of chemical bonds and internal electron transfer between the RGO and Li 4Ti 5O 12 components is evidenced by micro-Raman and X-ray photoelectron spectroscopy, showing the weakening of the carbon-carbon bonds and the formation of carbon-oxygen bonds. In comparison with the pristine Li 4Ti 5O 12 material, the Li 4Ti 5O 12-RGO nanocomposites display better anode performance with a larger discharge capacity of ∼175 mAhg -1, underscoring the merit of RGO hybridization in improving the electrode performance of bulk metal oxide. Diffuse reflectance UV-vis and photoluminescence spectroscopic analyses reveal a strong electrical connection between lithium titanate and RGO, which is mainly responsible for the observed improvement of the electrode performance upon the composite formation. In addition to the electrode performance, the photocatalytic activity of the lithium titanate for the generation of photocurrent can be remarkably enhanced by the coupling with RGO, confirming the usefulness of the present synthetic method in optimizing the photoinduced functionality of metal oxides. The solvothermal strategy presented here is also applicable for the synthesis of LiMn 2O 4-RGO nanocomposite showing much superior electrode performance over the pristine LiMn 2O 4. The experimental findings underscore that the present synthetic method can provide a universal way to not only immobilize multicomponent metal oxides on the surface of RGO nanosheets with a strong electrical connection but also improve the electrode and photocatalytic activity of these metal oxides. © 2012 American Chemical Society.
DOI
10.1021/jp301508k
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

BROWSE