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dc.contributor.author이상기*
dc.contributor.author김주현*
dc.date.accessioned2016-08-28T12:08:56Z-
dc.date.available2016-08-28T12:08:56Z-
dc.date.issued2012*
dc.identifier.issn0022-3263*
dc.identifier.otherOAK-8473*
dc.identifier.urihttps://dspace.ewha.ac.kr/handle/2015.oak/222367-
dc.description.abstractThe intramolecular alkylative reactivity and N/C selectivity of the various Blaise reaction intermediates, which are formed from the reaction of the Reformatsky reagents with ω-chloroalkyl nitriles, did not reach the synthetic potential as an entry to exo-cyclic enaminoesters. To circumvent this issue, various additives were investigated, among which the addition of NaHMDS dramatically enhanced the reactivity and N/C selectivity. This modification provided a highly efficient route for the synthesis of various N-fused heterocyclic compounds, as it requires only two steps from nitriles. © 2012 American Chemical Society.*
dc.languageEnglish*
dc.titleChemoselective intramolecular alkylation of the Blaise reaction intermediates: Tandem one-pot synthesis of exo -cyclic enaminoesters and their applications toward the synthesis of N -heterocyclic compounds*
dc.typeArticle*
dc.relation.issue3*
dc.relation.volume77*
dc.relation.indexSCI*
dc.relation.indexSCIE*
dc.relation.indexSCOPUS*
dc.relation.startpage1560*
dc.relation.lastpage1565*
dc.relation.journaltitleJournal of Organic Chemistry*
dc.identifier.doi10.1021/jo201964a*
dc.identifier.wosidWOS:000300462700035*
dc.identifier.scopusid2-s2.0-84863012859*
dc.author.googleKim J.H.*
dc.author.googleShin H.*
dc.author.googleLee S.-G.*
dc.contributor.scopusid이상기(15082786300)*
dc.contributor.scopusid김주현(57207894284)*
dc.date.modifydate20240123104103*
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자연과학대학 > 화학·나노과학전공 > Journal papers
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