Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 이상기 | * |
dc.contributor.author | 김주현 | * |
dc.date.accessioned | 2016-08-28T12:08:56Z | - |
dc.date.available | 2016-08-28T12:08:56Z | - |
dc.date.issued | 2012 | * |
dc.identifier.issn | 0022-3263 | * |
dc.identifier.other | OAK-8473 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/222367 | - |
dc.description.abstract | The intramolecular alkylative reactivity and N/C selectivity of the various Blaise reaction intermediates, which are formed from the reaction of the Reformatsky reagents with ω-chloroalkyl nitriles, did not reach the synthetic potential as an entry to exo-cyclic enaminoesters. To circumvent this issue, various additives were investigated, among which the addition of NaHMDS dramatically enhanced the reactivity and N/C selectivity. This modification provided a highly efficient route for the synthesis of various N-fused heterocyclic compounds, as it requires only two steps from nitriles. © 2012 American Chemical Society. | * |
dc.language | English | * |
dc.title | Chemoselective intramolecular alkylation of the Blaise reaction intermediates: Tandem one-pot synthesis of exo -cyclic enaminoesters and their applications toward the synthesis of N -heterocyclic compounds | * |
dc.type | Article | * |
dc.relation.issue | 3 | * |
dc.relation.volume | 77 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 1560 | * |
dc.relation.lastpage | 1565 | * |
dc.relation.journaltitle | Journal of Organic Chemistry | * |
dc.identifier.doi | 10.1021/jo201964a | * |
dc.identifier.wosid | WOS:000300462700035 | * |
dc.identifier.scopusid | 2-s2.0-84863012859 | * |
dc.author.google | Kim J.H. | * |
dc.author.google | Shin H. | * |
dc.author.google | Lee S.-G. | * |
dc.contributor.scopusid | 이상기(15082786300) | * |
dc.contributor.scopusid | 김주현(57207894284) | * |
dc.date.modifydate | 20240123104103 | * |