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dc.contributor.author남원우-
dc.contributor.author서미숙-
dc.contributor.author이용민-
dc.date.accessioned2017-08-28T22:34:28Z-
dc.date.available2017-08-28T22:34:28Z-
dc.date.issued2011-
dc.identifier.issn0002-7863-
dc.identifier.otherOAK-8324-
dc.identifier.urihttp://dspace.ewha.ac.kr/handle/2015.oak/222240-
dc.description.abstractA mononuclear non-heme manganese(IV)-oxo complex has been synthesized and characterized using various spectroscopic methods. The Mn(IV)-oxo complex shows high reactivity in oxidation reactions, such as C-H bond activation, oxidations of olefins, alcohols, sulfides, and aromatic compounds, and N-dealkylation. In C-H bond activation, the Mn(IV)-oxo complex can activate C-H bonds as strong as those in cyclohexane. It is proposed that C-H bond activation by the non-heme Mn(IV)-oxo complex does not occur via an oxygen-rebound mechanism. The electrophilic character of the non-heme Mn(IV)-oxo complex is demonstrated by a large negative ρ value of -4.4 in the oxidation of para-substituted thioanisoles. © 2011 American Chemical Society.-
dc.languageEnglish-
dc.titleA highly reactive mononuclear non-heme manganese(IV)-oxo complex that can activate the strong C-H bonds of alkanes-
dc.typeArticle-
dc.relation.issue50-
dc.relation.volume133-
dc.relation.indexSCI-
dc.relation.indexSCIE-
dc.relation.indexSCOPUS-
dc.relation.startpage20088-
dc.relation.lastpage20091-
dc.relation.journaltitleJournal of the American Chemical Society-
dc.identifier.doi10.1021/ja208523u-
dc.identifier.wosidWOS:000298713600017-
dc.identifier.scopusid2-s2.0-83755181358-
dc.author.googleWu X.-
dc.author.googleSeo M.S.-
dc.author.googleDavis K.M.-
dc.author.googleLee Y.-M.-
dc.author.googleChen J.-
dc.author.googleCho K.-B.-
dc.author.googlePushkar Y.N.-
dc.author.googleNam W.-
dc.contributor.scopusid남원우(7006569723)-
dc.contributor.scopusid이용민(36546331100;35233855500)-
dc.date.modifydate20170601133749-
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