Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | 서미숙 | * |
dc.contributor.author | 이용민 | * |
dc.date.accessioned | 2016-08-28T12:08:44Z | - |
dc.date.available | 2016-08-28T12:08:44Z | - |
dc.date.issued | 2011 | * |
dc.identifier.issn | 0002-7863 | * |
dc.identifier.other | OAK-8324 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/222240 | - |
dc.description.abstract | A mononuclear non-heme manganese(IV)-oxo complex has been synthesized and characterized using various spectroscopic methods. The Mn(IV)-oxo complex shows high reactivity in oxidation reactions, such as C-H bond activation, oxidations of olefins, alcohols, sulfides, and aromatic compounds, and N-dealkylation. In C-H bond activation, the Mn(IV)-oxo complex can activate C-H bonds as strong as those in cyclohexane. It is proposed that C-H bond activation by the non-heme Mn(IV)-oxo complex does not occur via an oxygen-rebound mechanism. The electrophilic character of the non-heme Mn(IV)-oxo complex is demonstrated by a large negative ρ value of -4.4 in the oxidation of para-substituted thioanisoles. © 2011 American Chemical Society. | * |
dc.language | English | * |
dc.title | A highly reactive mononuclear non-heme manganese(IV)-oxo complex that can activate the strong C-H bonds of alkanes | * |
dc.type | Article | * |
dc.relation.issue | 50 | * |
dc.relation.volume | 133 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 20088 | * |
dc.relation.lastpage | 20091 | * |
dc.relation.journaltitle | Journal of the American Chemical Society | * |
dc.identifier.doi | 10.1021/ja208523u | * |
dc.identifier.wosid | WOS:000298713600017 | * |
dc.identifier.scopusid | 2-s2.0-83755181358 | * |
dc.author.google | Wu X. | * |
dc.author.google | Seo M.S. | * |
dc.author.google | Davis K.M. | * |
dc.author.google | Lee Y.-M. | * |
dc.author.google | Chen J. | * |
dc.author.google | Cho K.-B. | * |
dc.author.google | Pushkar Y.N. | * |
dc.author.google | Nam W. | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | 이용민(36546331100;35233855500;57192113229) | * |
dc.date.modifydate | 20240130092654 | * |