Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Shunichi Fukuzumi | * |
dc.date.accessioned | 2016-08-28T12:08:34Z | - |
dc.date.available | 2016-08-28T12:08:34Z | - |
dc.date.issued | 2011 | * |
dc.identifier.issn | 1477-9226 | * |
dc.identifier.other | OAK-8206 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/222139 | - |
dc.description.abstract | The crystal structure of an N 2-encapusulated MOF, which is stable under open-air conditions at ambient temperature, was determined by single-crystal X-ray diffraction at 123 K. The crystal MOF of [HSm{V IVO(TPPS)}] n designed to have 1-D channels periodically constricted by porphyrins planes adsorbed N 2 at 77 K. The adsorbed N 2 molecules remained in the 1-D channels even after warming to ambient temperature. The single-crystal structure of [HSm{V IVO(TPPS)} ] n⊃N 2 determined by X-ray diffraction indicated that N 2 molecules trapped in the constricted parts block other N 2 molecules in 1-D channels from escaping from the MOF. Such a unique encapsulation mode provides a promising approach toward designing novel MOFs with high gas storage capacity at ambient temperature. © 2011 The Royal Society of Chemistry. | * |
dc.language | English | * |
dc.title | X-Ray crystal structure of [HSm{V IVO(TPPS)}] n and encapsulation of nitrogen molecules in 1-D channels | * |
dc.type | Article | * |
dc.relation.issue | 48 | * |
dc.relation.volume | 40 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 12826 | * |
dc.relation.lastpage | 12831 | * |
dc.relation.journaltitle | Dalton Transactions | * |
dc.identifier.doi | 10.1039/c1dt10956a | * |
dc.identifier.wosid | WOS:000297560000006 | * |
dc.identifier.scopusid | 2-s2.0-82555193809 | * |
dc.author.google | Chen W.-T. | * |
dc.author.google | Yamada Y. | * |
dc.author.google | Liu G.-N. | * |
dc.author.google | Kubota A. | * |
dc.author.google | Ichikawa T. | * |
dc.author.google | Kojima Y. | * |
dc.author.google | Guo G.-C. | * |
dc.author.google | Fukuzumi S. | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.date.modifydate | 20240401081001 | * |