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Proton-coupled electron shuttling in a covalently linked ruthenium-copper heterodinuclear complex

Title
Proton-coupled electron shuttling in a covalently linked ruthenium-copper heterodinuclear complex
Authors
Ishizuka T.Tobita K.Yano Y.Shiota Y.Yoshizawa K.Fukuzumi S.Kojima T.
Ewha Authors
Shunichi Fukuzumi
SCOPUS Author ID
Shunichi Fukuzumiscopus
Issue Date
2011
Journal Title
Journal of the American Chemical Society
ISSN
0002-7863JCR Link
Citation
vol. 133, no. 46, pp. 18570 - 18573
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
A heterodinuclear complex based on a RuII-TPA [TPA = tris(2-pyridylmethyl)amine] complex having a peripheral CuII (bpy)2 (bpy = 2,2'-bipyridine) group bonded through an amide linkage displayed reversible intramolecular electron transfer between the Ru and Cu complex units that can be controlled by protonation and deprotonation of the bridging amide moiety. © 2011 American Chemical Society.
DOI
10.1021/ja208141b
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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