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Isolation and structural characterization of the elusive 1:1 adduct of hydrazine and carbon dioxide

Title
Isolation and structural characterization of the elusive 1:1 adduct of hydrazine and carbon dioxide
Authors
Lee B.Kang S.H.Kang D.Lee K.H.Cho J.Nam W.Han O.H.Hur N.H.
Ewha Authors
남원우조재흥
SCOPUS Author ID
남원우scopus
Issue Date
2011
Journal Title
Chemical Communications
ISSN
1359-7345JCR Link
Citation
vol. 47, no. 40, pp. 11219 - 11221
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
A solid hydrazine was isolated as a crystalline powder by reacting aqueous hydrazine with supercritical CO 2. Its structure determined by single crystal X-ray diffraction shows a zwitterionic form of NH 3 +NHCO 2 -. The solid hydrazine is remarkably stable but is as reactive as liquid hydrazine even in the absence of solvents. © 2011 The Royal Society of Chemistry.
DOI
10.1039/c1cc14542h
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자연과학대학 > 화학·나노과학전공 > Journal papers
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