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Oxidative properties of a nonheme Ni(ii)(O 2) complex: Reactivity patterns for C-H activation, aromatic hydroxylation and heteroatom oxidation

Title
Oxidative properties of a nonheme Ni(ii)(O 2) complex: Reactivity patterns for C-H activation, aromatic hydroxylation and heteroatom oxidation
Authors
Latifi R.Tahsini L.Kumar D.Sastry G.N.Nam W.De Visser S.P.
Ewha Authors
남원우
SCOPUS Author ID
남원우scopus
Issue Date
2011
Journal Title
Chemical Communications
ISSN
1359-7345JCR Link
Citation
vol. 47, no. 38, pp. 10674 - 10676
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Density functional theory calculations on the reactivity of a Ni(ii)-superoxo complex in C-H bond activation, aromatic hydroxylation and heteroatom oxidation reactions have been explored; the Ni(ii)-superoxo complex is able to react with substrates with weak C-H bonds and PPh 3. © 2011 The Royal Society of Chemistry.
DOI
10.1039/c1cc13993b
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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