View : 28 Download: 0

Metal-free oxygenation of cyclohexane with oxygen catalyzed by 9-mesityl-10-methylacridinium and hydrogen chloride under visible light irradiation

Title
Metal-free oxygenation of cyclohexane with oxygen catalyzed by 9-mesityl-10-methylacridinium and hydrogen chloride under visible light irradiation
Authors
Ohkubo K.Fujimoto A.Fukuzumi S.
Ewha Authors
Shunichi Fukuzumi
SCOPUS Author ID
Shunichi Fukuzumiscopus
Issue Date
2011
Journal Title
Chemical Communications
ISSN
1359-7345JCR Link
Citation
vol. 47, no. 30, pp. 8515 - 8517
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Photooxygenation of cyclohexane by O 2 occurs efficiently under visible-light irradiation of an O 2-saturated acetonitrile solution containing 9-mesityl-10-methylacridinium ions (Acr +-Mes) and HCl to yield cyclohexanone, cyclohexanol and hydrogen peroxide. The photocatalytic reaction is initiated by electron transfer from Cl - to the mesitylene radical cation moiety. © The Royal Society of Chemistry 2011.
DOI
10.1039/c1cc12534f
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

BROWSE