Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | 서미숙 | * |
dc.date.accessioned | 2016-08-28T12:08:43Z | - |
dc.date.available | 2016-08-28T12:08:43Z | - |
dc.date.issued | 2011 | * |
dc.identifier.issn | 2041-6520 | * |
dc.identifier.other | OAK-7619 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/221657 | - |
dc.description.abstract | A highly reactive mononuclear nonheme iron(IV)-oxo complex with a low-spin (S = 1) triplet ground state in both C-H bond activation and oxo transfer reactions is reported; this nonheme iron(IV)-oxo complex is more reactive than an iron(IV)-oxo porphyrin π-cation radical (i.e., a model of cytochrome P450 compound I) and is the most reactive species in kinetic studies among nonheme iron(IV)-oxo complexes reported so far. DFT calculations support the experimental results with extremely low activation barriers in the C-H bond activation of cyclohexane and 1,4-cyclohexadiene. The DFT calculations reveal that the S = 1 state is set up to easily lead to the highly reactive S = 2 high-spin iron(IV)-oxo species. © The Royal Society of Chemistry 2011. | * |
dc.language | English | * |
dc.title | A mononuclear nonheme iron(IV)-oxo complex which is more reactive than cytochrome P450 model compound I | * |
dc.type | Article | * |
dc.relation.issue | 6 | * |
dc.relation.volume | 2 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 1039 | * |
dc.relation.lastpage | 1045 | * |
dc.relation.journaltitle | Chemical Science | * |
dc.identifier.doi | 10.1039/c1sc00062d | * |
dc.identifier.wosid | WOS:000290629900006 | * |
dc.identifier.scopusid | 2-s2.0-79957845133 | * |
dc.author.google | Seo M.S. | * |
dc.author.google | Kim N.H. | * |
dc.author.google | Cho K.-B. | * |
dc.author.google | So J.E. | * |
dc.author.google | Park S.K. | * |
dc.author.google | Clemancey M. | * |
dc.author.google | Garcia-Serres R. | * |
dc.author.google | Latour J.-M. | * |
dc.author.google | Shaik S. | * |
dc.author.google | Nam W. | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.date.modifydate | 20240116111857 | * |