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Low pressure ethenolysis of renewable methyl oleate in a microchemical system

Title
Low pressure ethenolysis of renewable methyl oleate in a microchemical system
Authors
Park C.P.Van Wingerden M.M.Han S.-Y.Kim D.-P.Grubbs R.H.
Ewha Authors
한소엽
SCOPUS Author ID
한소엽scopus
Issue Date
2011
Journal Title
Organic Letters
ISSN
1523-7060JCR Link
Citation
vol. 13, no. 9, pp. 2398 - 2401
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Chemical equations presented. A microchemical system for ethenolysis of renewable methyl oleate was developed, in which the dual-phase, microfluidic design enabled efficient diffusion of ethylene gas into liquid methyl oleate through an increased contact area. The increased mass transfer of ethylene favored the formation of desired commodity chemicals with significantly suppressed homometathesis when compared to the bulk system. In addition to higher selectivity and conversion, this system also provides the typical advantages of a microchemical system, including the possibility of convenient scale-up. © 2011 American Chemical Society.
DOI
10.1021/ol200634y
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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