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Construction, photoluminescence, and catalytic reactivity study of Cd(II) complexes containing amide ligand with hydrogen-bond capable backbone: 1-Dimensional looped chain

Title
Construction, photoluminescence, and catalytic reactivity study of Cd(II) complexes containing amide ligand with hydrogen-bond capable backbone: 1-Dimensional looped chain
Authors
Lee T.G.Lee J.H.Hyun M.Y.Jang S.P.Lee H.G.Kim C.Kim S.-J.Kim Y.
Ewha Authors
김성진김영미
SCOPUS Author ID
김성진scopus; 김영미scopus
Issue Date
2010
Journal Title
Inorganic Chemistry Communications
ISSN
1387-7003JCR Link
Citation
vol. 13, no. 12, pp. 1493 - 1496
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Three new Cd(II) complexes containing 3-bpdb ligands with amide moiety as hydrogen-bond capable backbone, formulated as [Cd(3-bpdb)X2] n (3-bpdb = N,N′-dipyridin-3-ylpyridine-2,6-dicarboxamide, X = Cl (1), Br (2), and I (3)), have been synthesized. All three compounds show 1-dimensional looped chain structures, and intra- and inter-molecular hydrogen bonding interactions provide 2-dimensional sheets. Among three pausible conformers of ligand 3-bpdb, all three halide compounds show only anti-anti conformation to provide 1-dimensional looped chains. In addition, emissions of compounds 1 and 2 were observed at 424 nm and 431 nm, respectively, suggesting that they might be a good candidate for a potential hybrid inorganic-organic photoactive material. Moreover, compounds 1-3 carried out an efficient transesterification of vinyl acetate. © 2010 Elsevier B.V. All rights reserved.
DOI
10.1016/j.inoche.2010.08.025
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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