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Cupric superoxo-mediated intermolecular C-H activation chemistry

Title
Cupric superoxo-mediated intermolecular C-H activation chemistry
Authors
Peterson R.L.Himes R.A.Kotani H.Suenobu T.Tian L.Siegler M.A.Solomon E.I.Fukuzumi S.Karlin K.D.
Ewha Authors
Shunichi FukuzumiKenneth D. Karlin
SCOPUS Author ID
Shunichi Fukuzumiscopus
Issue Date
2011
Journal Title
Journal of the American Chemical Society
ISSN
0002-7863JCR Link
Citation
vol. 133, no. 6, pp. 1702 - 1705
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The new cupric superoxo complex [LCu II(O 2 -)] +, which possesses particularly strong O-O and Cu-O bonding, is capable of intermolecular C-H activation of the NADH analogue 1-benzyl-1,4-dihydronicotinamide (BNAH). Kinetic studies indicated a first-order dependence on both the Cu complex and BNAH with a deuterium kinetic isotope effect (KIE) of 12.1, similar to that observed for certain copper monooxygenases. © 2011 American Chemical Society.
DOI
10.1021/ja110466q
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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