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자연과학대학
화학·나노과학전공
Journal papers
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Cupric superoxo-mediated intermolecular C-H activation chemistry
Title
Cupric superoxo-mediated intermolecular C-H activation chemistry
Authors
Peterson R.L.
;
Himes R.A.
;
Kotani H.
;
Suenobu T.
;
Tian L.
;
Siegler M.A.
;
Solomon E.I.
;
Fukuzumi S.
;
Karlin K.D.
Ewha Authors
Shunichi Fukuzumi
;
Kenneth D. Karlin
SCOPUS Author ID
Shunichi Fukuzumi
Issue Date
2011
Journal Title
Journal of the American Chemical Society
ISSN
0002-7863
Citation
Journal of the American Chemical Society vol. 133, no. 6, pp. 1702 - 1705
Indexed
SCI; SCIE; SCOPUS
Document Type
Article
Abstract
The new cupric superoxo complex [LCu II(O 2 -)] +, which possesses particularly strong O-O and Cu-O bonding, is capable of intermolecular C-H activation of the NADH analogue 1-benzyl-1,4-dihydronicotinamide (BNAH). Kinetic studies indicated a first-order dependence on both the Cu complex and BNAH with a deuterium kinetic isotope effect (KIE) of 12.1, similar to that observed for certain copper monooxygenases. © 2011 American Chemical Society.
DOI
10.1021/ja110466q
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