Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | 조재흥 | * |
dc.contributor.author | Kenneth D. Karlin | * |
dc.date.accessioned | 2016-08-28T12:08:19Z | - |
dc.date.available | 2016-08-28T12:08:19Z | - |
dc.date.issued | 2011 | * |
dc.identifier.issn | 1477-9226 | * |
dc.identifier.other | OAK-7356 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/221431 | - |
dc.description.abstract | A copper(ii)-hydroperoxo complex, [Cu(Me 6-tren)(OOH)] + (2), and a copper(ii)-cumylperoxo complex, [Cu(Me 6-tren)(OOC(CH 3) 2Ph)] + (3), were synthesized by reacting [Cu(Me 6-tren)(CH 3CN)] 2+ (1) with H 2O 2 and cumyl-OOH, respectively, in the presence of triethylamine. These intermediates, 2 and 3, were successfully characterized by various physicochemical methods such as UV-vis, ESI-MS, resonance Raman and EPR spectroscopies, leading us to propose structures of the Cu(ii)-OOR species with a trigonal-bipyramidal geometry. Density functional theory (DFT) calculations provided geometric and electronic configurations of 2 and 3, showing trigonal bipyramidal copper(ii)-OOR geometries. These copper(ii)-hydroperoxo and -cumylperoxo complexes were inactive in electrophilic and nucleophilic oxidation reactions. © 2011 The Royal Society of Chemistry. | * |
dc.language | English | * |
dc.title | Spectroscopic and computational characterization of Cu II-OOR (R = H or cumyl) complexes bearing a Me 6-tren ligand | * |
dc.type | Article | * |
dc.relation.issue | 10 | * |
dc.relation.volume | 40 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 2234 | * |
dc.relation.lastpage | 2241 | * |
dc.relation.journaltitle | Dalton Transactions | * |
dc.identifier.doi | 10.1039/c0dt01036g | * |
dc.identifier.wosid | WOS:000287665000023 | * |
dc.identifier.scopusid | 2-s2.0-79951879414 | * |
dc.author.google | Choi Y.J. | * |
dc.author.google | Cho K.-B. | * |
dc.author.google | Kubo M. | * |
dc.author.google | Ogura T. | * |
dc.author.google | Karlin K.D. | * |
dc.author.google | Cho J. | * |
dc.author.google | Nam W. | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | 조재흥(7403536408) | * |
dc.date.modifydate | 20240116111857 | * |