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Poly[[bis[μ-1,2-bis(4-pyridyl)ethene]-bis(trichloroacetato)cadmium(II)] monohydrate]

Title
Poly[[bis[μ-1,2-bis(4-pyridyl)ethene]-bis(trichloroacetato)cadmium(II)] monohydrate]
Authors
Kim J.H.Kim C.Kim Y.
Ewha Authors
김영미
SCOPUS Author ID
김영미scopus
Issue Date
2011
Journal Title
Acta Crystallographica Section E: Structure Reports Online
ISSN
1600-5368JCR Link
Citation
vol. 67, no. 1, pp. m3 - m4
Indexed
SCOPUS WOS scopus
Abstract
In the crystal structure of the title compound, {[Cd(C2Cl 3O2)2- (C12H10N 2)2]·H2O}n, the CdII ion lies on a twofold rotation axis and 1,2-bis(4-pyridyl)ethene ligands bridge symmetryrelated CdII ions, forming a two-dimensional structure. Two trichloroacetate ligands complete the coordination around the CdII ion, forming a distorted octahedral environment. In the crystal, solvent water molecules, which also lie on twofold rotation axes, form intermolecular O - H⋯O hydrogen bonds, which connect the two-dimensional structure into a three-dimensional network. The crystal studied was an inversion twin, the refined ratio of twin components being 0.75 (4):0.25 (4).
DOI
10.1107/S1600536810049457
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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