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A low-spin ruthenium(IV)-oxo complex: Does the spin state have an impact on the reactivity?

Title
A low-spin ruthenium(IV)-oxo complex: Does the spin state have an impact on the reactivity?
Authors
Kojima T.Hirai Y.Ishizuka T.Shiota Y.Yoshizawa K.Ikemura K.Ogura T.Fukuzumi S.
Ewha Authors
Shunichi Fukuzumi
SCOPUS Author ID
Shunichi Fukuzumiscopus
Issue Date
2010
Journal Title
Angewandte Chemie - International Edition
ISSN
1433-7851JCR Link
Citation
vol. 49, no. 45, pp. 8449 - 8453
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Spin doesn't matter: A ruthenium(II)-aqua complex bearing a pentadentate pyridylamine with a carboxylate group as a ligand affords a seven-coordinate low-spin (S=0) ruthenium(IV)-oxo complex (see structure) by oxidation through proton-coupled electron transfer. Comparison of the reactivity of the low-spin and an intermediate-spin (S=1) Ru IV-oxo complexes revealed that the spin state does not affect the reactivity of catalytic oxidation of organic compounds. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
DOI
10.1002/anie.201002733
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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